Ah good, so that can be ruled out.Thanks for the IM and reply.
I have only owned the car for a month or so (and been in the garage most that time) and it has showed the fault pretty much ever drive except when I test drove it and on the 2 1/2 hour drive home.
The pump fitted 04E.121.600.CB which I have been told was superseded 01/09/2021 by 04E.121.600.CS which is the same as you stated. The fact it shows Skoda on the part itself is confusing but seems the correct part is fitted all be it a previous version. Seat technical have finally come back stated the below:
'They agreed with us that the holding of pressure overnight, to the extent it is, can put the suspension elsewhere. They also agreed blockages can of course cause cooling system anomalies depending where the blockage is. They aren't ruling out cylinder head issues, still recommending removal for inspection of coolant channels, gasket etc. Other than that there is no real guidance from their end they can offer on where this blockage could possibly be. If not removing the head, it will be a case of things like, attempting radiator flushes. Removing coolant pipes and trying to check the one way valves by flowing water through them. One hypothesis is that a coolant leak sealer could have been used at some point in its life, the first time the coolant pump was replaced was due to overheating and a leak from it. This could possibly cause restrictions in the system and cause misreading's from sensors. But again, this is speculation.'
At this point I think I may get the car back and strip all the coolant system before I even think about taking the head off. What do you think?
I struggle to see how the head gasket could be at fault - following that you have checked and no exhaust gasses were in the coolant. I would leave taking the head off as a last resort until you can guarantee the cooling system is 100% ok.
Manual here:
Have a look at the cooling system - post 2013 - which has the additional bleed circuit I noticed on the pump housing.
It actually looks 'simpler' than my TDI cooling system - I can't see any one way valves, so draining and filling looks a fairly standard affair.
There are a few heat exchangers which could be the first thing to block following 'stop leak gunk'.