Stock rear brakes on all FWD Leons except Cupra R are 232mm, solid.
Cupra R and 4WD Audi TT have 256mm, vented.
To fit 256mm rear brakes from a 4WD to a FWD Leon, a spacer is needed to push the caliper carrier 6mm outwards:
There are many producers, some do it in aluminium, others in steel. Steel is better, it won't corrode as aluminium mounted on steel does in salty environments. N & M Performance Parts (eBay: nandmperformanceparts ) is based in the UK and provides rather cheaply a spacer made from cadmium-plated steel.
All calipers (indeed, all Seat rear calipers from 1991 to 2006) use the same pad.
To keep the original caliper, there are 4 options:
239x9 mm disc - Skoda Octavia 1.8T/150 4WD, pre-facelift
Fits on the same caliper, needs the 6mm spacer to move the caliper outwards.
Gain in braking torque about 3%.
280x9mm disc - Eurospec Sport EBK 698
280 G/J4 RE
Fits on the same caliper, comes with own spacer to mount the caliper carrier.
Gain in braking torque about 26%
308x9mm disc - ECS Tuning ES#803.
Fits on the same caliper, comes with own spacer to mount the caliper carrier.
Gain in braking torque about 41%
330x9mm disc - Tarox KMVW0540
Fits on the same caliper, comes with own spacer to mount the caliper carrier.
Gain in braking torque about 53%.
Does not fit the 16" spare wheel, needs at least 17".
For the ventilated disc system (caliper + carrier + hubs / spacers) there are: stock 256mm, first oversize 280x22mm, larger ECS 306x22mm, then Tarox 330x22mm.
Own experience:
Had to change my rear brake discs (>133000kms / >82000 miles, heavily worn). On Brembo Max discs (coated and slotted, no drills) prices for 232mm and 239mm solid discs were similar.
Asked for a set of 239mm discs. Already had a steel 6mm spacer kit for an older project. All other original parts fit by design.
When fitted, the dust shield has to be bent back with pliers.
The gain in brake torque is insignificant. Advantage is mostly looks: by having a slightly bigger disc and moving it outwards to the wheel, they don't look as ridiculously puny as stock 232mm.