Do you have access to
OBD11 or VCDS, There is a section called readiness
Monitoring status since erasing DTC memory
Number of emission relevant DTC memory entries
Malfunction indicator lamp
Monitoring of ignition misfires
Monitoring of fuel system
Monitoring of entire system
Catalytic converter monitoring
Monitoring of catalytic converter at operating temperature
Monitoring of tank ventilation system
Monitoring of Secondary Air Injection (AIR) System
Monitoring of oxygen sensor
Monitoring of oxygen sensor heater
Monitoring of EGR and camshaft adjustment
Read more:
http://forum.obdeleven.com/thread/3262/control-unit-setup#ixzz5HIipXefu
Readiness is a group of "parameters" (usually 8 x binary Bits) in the engine module which indicate the health of the car's emission systems. A state of 0 means "fail" and 1 means "passed". Whenever you bulk clear DTCs, ALL 8 x bits are set to the "fail" state - if your car doesn't have all 8 x emission test capabilities, those Bits will automatically be reset to 1.
Using these hopefully you can test to see if warming up the cat makes any difference.