The fuel gauge is divided into 1/8 segments for most of its range, so each segment should be 'worth' 5.6 litres for a 45 litre tank. The
problem is that we don't know whether the fuel is just under the level required to light the next segment, or just over the level required to light the existing segment.
So you can only know your fuel level to an accuracy of plus or minus 5.6ltrs - and that assumes that the fuel tank sender is accurate. I fill my petrol 1.2TSi when the petrol warning light comes on and that seems to consistantly need 39 litres - or seven 1/8 segments. That leaves 6 litres in the tank, which is the remaining 1/8th segment on the display.