Use the figures on the line which has a symbol of three people and a suitcase, use the figures on the Comfort line. (unless you are always fully loaded)
Of the two values given the higher pressure will be for the front tyres.
The warning may be due to the low temperatures. Use your tyre pressure guage to check, the warning comes up because one tyre is different rather than directly measuring pressures. So if the pressures are roughly correct on each axle then it may be a false warning.
Pump the tyres to the correct value then reset the TPWS (tyre pressure warning system) as below:
press CAR > Setup> Tyres > set pressure > confirm ( or something similar).