If your cooling system won't hold pressure - this is the FIRST
problem you should address.
I would double check your pressure tester to ensure it is a real leak and not just the pressure tester leaking but supposing your tester is air tight, first thing to do is find the leak.
To name a few possible culprits:
main coolant pump
heater matrix o-rings (mine leaked and wet the carpet as had gone square)
radiator + pipework/o rings
air to water heat exchanger (as mentioned can check with a borescope, I found water in mine but must be a small heat dependant leak as mine passes my pressure test)
egr cooler
head gasket
These cooling systems are very complicated with 3x pumps and many one way valves.
Normally, vacuum fill tools need an air line supply - and work via the venturi principle - blowing high speed air past an orifice creates a vacuum.
First empty the system.
Then pull a vacuum.
Then open the valve on your vacuum fill tool - which sucks on the tube submerged in your bottle of coolant and fills your system only with coolant (don't let this tube suck air!).
Once is stops sucking, top off the header tank if required, and then you do the VCDS bleed as a final step.