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I used Hammerite Smooth spray and the finish is better than the cupra factory finish red calipers.

Use the brakes as if you're bedding new pads in for a week otherwise Hammerite can melt before it hardens fully
 
i used halfords caliper paint on the frount callipers and used hammerite on the back drums about ayear and a half ago and just freshed them up couple of weeks ago. was not any difference would say that both paints were simmiler tbh.
 
I did a thread on this for a leon cupra and to be honest you dont need to take anything but the wheel off, just make sure you mask up everything else if your not confident with a paint brush. its very easy and if you use the right stuff it looks very good indeed