I was mainly making reference to what I did on my S4, but most of it carries across to all these newish engines.
Maybe you should search using Google for "changing coolant in a
SEAT Leon MK3, when I last looked, the internet was awash with these guides, there were quite a few for my B8 S4 and I'd be surprised if there are not any for this
SEAT Leon MK3 1.2TSI or maybe even the VW Golf same age or Skoda Octavia same age.
Coolant capacity, I only know the capacity of my B8 S4 and that became obvious only when I drained it down, someone in another forum quoted refilling a B8 S4 with 6 litres so I bought in more than that. I could not find that capacity figure anywhere in the official Audi
workshop manual, so I'd doubt if you will find it the one your were given a link to, which I found a bit annoying, why VW Group leave out that bit of info I can't say.
The one reason that I did not perform a full flushing with a hose followed up with reloading with warm/hot water and taking the car on a short trip, then dumping the water and backfilling with G12evo was, I was concerned that for the first time in my life, I could only buy ready mixed coolant from VW Group, and if I had left water in the system after flushing it out, ie did not manage to remove as much of the water as possible, I would have ended up having a lower strength coolant mix than I had intended to have.
By the way, to answer one of the questions you asked SuperV8, the charge cooler is the turbo charged air water/air intercooler on the inlet manifold, it has its own electric fan and it is separated flow wise from the common coolant circuit as the plan is to get the rest of the engine up to temperature as quickly as possible - but dumping accumulated/acquired heat out of the inlet air is desirable at all times.
Edit:- I'd be the first to acknowledge that some people will just be ploughing straight in and opening up these coolant systems and then refilling them with as much coolant as possible - and getting away with it, but why bother to take that risk if you are asking questions on how it is done.
I think that VW Group are quite laid back or secretive about exactly how long the factory loaded in coolant should be left in the system, I bought a pack of test strips in from America to check over my cars as for the first time in my life I've owned a car with a cam belt - and a separate water pump belt, and a car with a cam chain, prior to that all our cars had a water pump driven off the cam belt or behind the cam belt which meant the smart thing to do was to get the water pump and so coolant replaced every cam belt change or every other cam belt - so the coolant ended up being replaced at worst/longest every 8 - 10 years. My 2011 S4 is obviously now over 10 years old, so that is why I chose to replace the coolant. By the way, the test strips ended up getting too old to be trusted but I could see a change in the PH value which indicates that the coolant is degrading from being slightly alkaline towards being acidic and when that happens the corrosion protection has dropped. When you look at any other company selling that same coolant, all of which in VW Group world is manufactured by BASF, every single previous to G12evo product that appears in the aftermarket, quotes a
service life of maybe 3 years, now maybe that is just to keep the aftermarket suppliers in business, or is there another reason that we don't know about?
Another Edit:- then for cars that were filled up with G13 at the factory and have not got a "silicate top up pouch/capsule" in the reservoir - what is expected to be going on in these systems, I'd think that there there will be "early" protection depletion and so corrosion will kick in, another reason why I'm considering replacing what will be G13 in the cooling system of my wife's late July/early August build 2015 VW Polo, for the G12evo I seem to have left over from changing the coolant in my early February 2011 build S4 to G12evo. I just need to read through the recommendations for doing that job in my official VW Polo
workshop manual - and not just jump in and pull hoses off etc!