That will look spot on!

I have just had my wheels powdercoated black on my Red Cupra and it really suits it!
 
Not standard wheel but here's mine with team dynamic monza's in satin black. :D

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Thanks, would also like to see the oem ones

if you mean the black oem ones, if you go to the seat website, you can go to the spec your leon bit and tell it to put black orions on... it then shows you how it will look... this is the same pics as in the recent brochure I ordered (2008 I think).
 
Cant show you them on a yellow motor but here's my red one with the OEM 18inchers on it so you could do a bit of photoshop and see!

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imho it will look alot meaner (and better) with black rims.

I'll see if I can dig it out (cant remember the address off hand). but there is a web site where you take a side profile picture of you car, upload it and then you can choose the alloys you like and overlay them onto the car to see what they look like, not bad for a visual representation
 
powder coating will be more resistant to chips , bumps and scrapes , and more resisitant to cleaning chemicals , only down side is if you do get a chip or scratch you wont be able to just spray over it with paint , it will look silly.

i would go with powder coating mate.